INVESTIGACIÓN |
A continuación se detallan algunas de las publicaciones del área:
AÑO 2015
Serrano Martínez, José Luis; Lozano Rodríguez, Pedro; Sánchez Gómez, Gregorio; García Collado, Joaquín; Kapdi , Anannt R.; Sanghvi , Yogesh; Ardhapure “ Pd- imidate complexes as recyclable catalysts for the synthesis of C5-alkenylated pyrimidine nucleosides via Heck cross-coupling reaction”, RSC ADVANCES, 2015, 5, 24558-24563.
Serrano Martínez, José Luis; Pérez Pérez, José; García González, Luis; Sánchez Gómez, Gregorio; García Collado, Joaquín; Lozano Rodríguez, Pedro; Zende , V.; Kapdi , Anant R. N-heterocyclic-carbene complexes readily prepared from di-mu-hydroxopalladacycles catalyze the suzuki arylation of 9-bromophenanthrene, ORGANOMETALLICS, 2015, 34, 522-533
Luisa Lopez-Banet; M. Dolores Santana; Gabriel Garcia; Luis Lezama; Iván Da Silva, Jose Perez; Luis Garcia, Blocking and brinding ligands direct structure and magnetic properties of dimers of pentacoordinate nickel(II), DALTON TRANS, 2015, 44, 9504-9511
AÑO 2014
Anant R. Kapdi, Gopal Dhangar, Jose Luis Serrano, Jose Pérez, Luis García and Ian J. S. Fairlamb. [Pd(C N)(X)(PPh3)] palladacycles react with 2,4,6-trifluorophenyl boronic acid to give stable transmetallation products of the type [Pd(C N)(2,4,6-F3C6H2)(PPh3)]. CHEM. COMMUN., 2014,50, 9859-9861.
Perez, Jose; Serrano, J. Luis; da Silva, Ivan; Pérez, Eduardo; García, Luis. Ligand hierarchy on driving the crystal packing. Effect of supramolecular interactions on solid-state conformations adopted by saccharinate Pd(II) complexes. CRYSTENGCOMM., 2014, 16 (30),7124-7132.
Luisa Lopez-Banet; M. Dolores Santana; Maria Jose Piernas; Gabriel Garcia; Javier Cerezo; Alberto Requena; Jose Zuniga; Jose Perez; Luis Garcia. Structure and Spectroscopic Properties of Nickel Benzazolate Complexes with Hydrotris(pyrazolyl)borate Ligand. INORGANIC CHEMISTRY, 2014, 53 (11), 5502 - 5514.
Anant Kapdi; Vijay Gayakhe; Yogesh S. Sanghvi; Joaquin Garcia; Pedro Lozano; Ivan da Silva; Jose Perez; J. Luis Serrano. New water soluble Pd-imidate complexes as highly efficient catalysts for the synthesis of C5-arylated pyrimidine nucleosides. RSC ADVANCES, 2014, 4, 17567 - 17572.
Anant Kapdi; Gopal Dhangar; J. Luis Serrano; J. Antonio de Haro; Pedro Lozano García and Ian J. S. Fairlamb. [Pd(Phbz)(X)(PPh3)] palladacycles promote the base-free homocoupling of arylboronic acids in air at room temperature. RSC ADVANCES, 2014, 4, 55305-55312.
AÑO 2013
Jose Perez; Jose Luis Serrano; Jorge Enrique Granados; Luis Alberto Alcolea. Recovering palladium from its surplus complexes in research laboratories by solid state thermal treatment. RSC ADVANCES, 2013, 3 (14), 4558 -4567
M. Dolores Santana; Rocio Garcia-Bueno; Gabriel Garcia; Maria Jose Piernas; Jose Perez; Luis Garcia; Ignacio Lopez-Garcia. Benzazolate complexes of pentacoordinate nickel(II). Synthesis, spectroscopic study and luminescent response towards metal cations. POLYHEDRON, 2013, 61, 161 - 171.
Luisa Lopez-Banet; M. Dolores Santana; Gabriel Garcia; M. Jose Piernas; Luis Garcia; Jose Perez; Ainhoa Calderon-Casado; Gotzone Barandika. Crystal Structures and Spectroscopic and Theoretical Properties of Pentacoordinate Nickel(II) Complexes Containing Tris(pyrazolyl)borate and Quinolinate Ligands. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 24, 4280 - 4290.
Gregorio Sanchez; Joaquin Garcia; Malva Liu; Luis Garcia; Jose Perez; Eduardo Perez; Jose L. Serrano. Synthesis and characterization of cyclometallated palladium(II) complexes with 2-(diphenylphosphino)benzaldehyde. JOURNAL OF COORDINATION CHEMISTRY, 2013, 66 (16), 2919-2929.
Parin Shah, M. Dolores Santana, Joaquín García, J. Luis Serrano, Minal Naik, Suhas Pednekar,Anant R. Kapdim; [Pd(PPh3)2(saccharinate)2]: general catalyst for Suzuki-Miyaura, Negishi cross-coupling and C-H bond functionalization of coumaryl and pyrone substrates. TETRAHEDRON, 2013, 69, 1446-1453.
AÑO 2012
López-Banet , Luisa; Santana, Mª Dolores; García, Gabriel; Pérez, José; García, Luis; Lezama, Luis and Liu, Malva. Networks based on hydrogen-bonds containing phosphorus anions and tris(3,5-dimethylpyrazolyl)borate nickel(II) moieties. POLYHEDRON, Vol. 31. 2012. 575-586.
Santana, Mª Dolores; García-Bueno, Rocío; García, Gabriel; Sánchez, Gregorio; García, Joaquín; Kaédi, Anant R.; Naik, Minal; Pednekar, Suhas; Pérez, José; García, Luis; Pérez, Eduardo and Serrano, José Luis. Novel saccharinate-bridged palladium complexes for efficient C–O bond activation displaying promising luminescence properties. DALTON TRANSACTIONS. Vol. 41. 2012. 3832-3842.
Serrano, José Luis; Pérez, José; García, Luis; Sánchez, Gregorio; García, Joaquín; Kapdi, Anant R. and Tyagi, Kriti. New phospha-palladacycles: efficient catalysts in the formylation of aryl chlorides. RSC ADVANCES. Vol. 2. 2012. 12237-12244.
Pérez, José; García, Luis; Pérez, Eduardo; Serrano, José Luis and Kessler, Mathieu. Type conformations and pseudorotation interconversion path-way between conformations: A tool to study medium size (5–9 atoms) rings. JOURNAL OF MOLECULAR STRUCTURE. Vol. 1027. 2012. 186-199.
Kessler, Mathieu and Pérez, José. Equivalence properties of the Cremer & Pople puckering coordinates for N-membered rings. J. MATH. CHEM. Vol 50. 2012. 187-209.
AÑO 2011
Kessler, Mathieu; Pérez Pérez, José. 3D Superposition of chemical fragments for N-Membered rings: Application to conformational analisys .J. CHEMOMETRICS 2011, 25 0886-9383.
Serrano Martínez, José Luís; García Gonzalez, Luís; Pérez Pérez, José; Pérez Pardo, Eduardo; Galiana García, José Miguel; García Collado , Joaquín; Martínez , Marina; Sánchez Gómez , Gregorio; Da Silva , Ivan. New cyclometallated precursors of unsubstituted N- Phenylpyrazole[{PD(PHPZ)(L-X)}2] (X = ACO OR OH) and study of their rectivity towards selected ligands. DALTON TRANSACTIOS 2011, 40 1477-9226.
López-Banet , Luisa; Santana Lario , Dolores; García Sánchez , Gabriel; García González, Luis; Pérez Pérez, José; Rojo , Teófilo; Lezama , Luis; Costes , Jean-Pierre. Crystal structures and magnetic properties of nickel complexes with Hydrotris(Pyrazolyl) borate ligand and double Bridged by phosphate estres. INORGANIC CHEMISTRY 2011, 50 0020-1669. Pag: 437-443
Pérez Pérez, José; Carrascosa Fenol, Ramón; García Gonzalez, Luís; Barandika , G.; Calderón-Casado , A.; Pérez Pardo, Eduardo; Serrano Martínez, José Luís; Santana Lario, Maria Dolores. Coordination to metal centers: a tools to fix high energy conformations in organic molecules. Application to 2,4,4-trimethyl-1,5,9-triazacyclododec-1-Ene and related macrocycles. DALTON TRANSACTIONS 2011, 40 1477-9226. Pag: 9504-9511
Santana Lario , Maria Dolores; García-Bueno , Rocio; García Sánchez , Gabriel; Sánchez Gómez , Gregorio; García Collado , Joaquín; Pérez Pérez, José; García Gonzalez, Luís; Serrano Martínez, José Luís. Synthesis and luminescence properties of cyclopalladated complexed with S^N and O^N donor ligands. DALTON TRANSACTIONS 2011, 40 1477-9226. Pag: 3537-3546
Serrano Martínez, José Luís; García Gonzalez, Luís; Pérez Pérez, José; Pérez Pardo, Eduardo; García Collado , Joaquín; Sánchez Gómez , Gregorio; Sehnal , Petr; De Ornellas , Sara; Willianms, Thomas J; Fairlamb , Ian J.S. Synthesis and characterization of imie-palladacycles containing imidate PSEUDOHALIDE ligands: Efficient suzuki miyaura cross-coupling precatalysts and their avtivation to give pdoln species (L = PH. ORGANOMETALLICS 2011,30 0276-7333. Pag: 5095-5109
Santana Lario , Maria Dolores; García-Bueno , Rocio; García Sánchez , Gabriel; Sánchez Gómez , Gregorio; García Collado , Joaquín; Pérez Pérez, José; García Gonzalez, Luís; Serrano Martínez, José Luís. Luminescence properties of cyclopalladated complexes with schiff base ligands. INORGANICA CHIMICA ACTA 2011, 378 0020-1693. Pag: 49-55
Serrano Martínez, José Luís; Pérez Pérez, José; García Gonzalez, Luís; KapdiI , Anant R.; Sánchez Gómez , Gregorio; García Collado , Joaquín; Martínez Carmona, Marina. Bis(Imidate)Palladium(II) complexes with labile ligands. Mimics of classical Pecursosrs?. DALTON TRANSACTIONS 2011,40 1477-9226. Pag:12676-12689
AÑO 2010
J. Perez, E. Perez, R. Carrascosa, A. Espinosa, L. Garcia, J. L. Serrano, Solid state conformational preferences of the core (X = O, S) in transition metal complexes. Journal of Molecular Structure 2010, 968 52-58.
G. Sanchez, J. Garcia, J. L. Serrano, L. Garcia, J. Perez, G. Lopez, Homoleptic palladium complexes with phosphine-amide or iminophosphine ligands. Inorganica Chimica Acta 2010, 363 1084-1091.
M.D. Santana, R. García-Bueno, G. García, J. Pérez, L. García, M. Monge, A. Laguna. Luminiscence Of Five-Coordianted Nickel(II) Complexes With Substituted-8-Hydroxyquinolines And Macrociclic Ligands. Dalton Transactions 2010, 39, 1797-1806.
Rocío García-Bueno, María Dolores Santana, Gregorio Sánchez, Joaquín García, Gabriel García, José Pérez, Luis García, Mono- And Bidentate Imidates Of Five-Coordinate Nickel(Ii) With Macrocyclic Ligands: Spectroscopic And Photophysical Properties. Dalton Transactions 2010, 39, 5728-5736.
AÑO 2009
J. Perez, A. Espinosa, J. M. Galiana, E. Perez, J. L. Serrano, M. A. G. Aranda, M. Insausti, Orthogonal non-covalent binding forces in solid state supramolecular herringbone-shaped "interlocked dimers". Pseudopolymorphism in [(ppy)Pd(mu-pz)](2) (ppy=2-(2-pyridyl)phenyl, pz = pyrazol-1-yl) complex. Dalton Transactions 2009, 9625-9636.
R. García-Bueno, M.D. Santana, G. Sánchez, J. García , G. García, J. Pérez And L. García, Spectroscopic And Structural Characterization Of O,O’-(Diphenylphosphineoxide)-Amidate And Acetylacetonate Complexes Of Pentacoordinate Nickel(II).Journal Of Organometallic Chemistry. 2009, 694, 316-322.
A. L. Ortiz, F.L. Cumbrera, J. Pérez, J.J. Meléndez-Martínez, L. Palatinus, Crystal Structure Of [NBu4]2[Pd2{C4(COOMe)4}2(μ-OH)2] Determined Ab Initio By Charge Flipping, Journal Of Alloys And Compounds, 2009, 467, 322-326.
Angel L. Ortiz, Francisco L. Cumbrera, José Pérez, Beatriz del Vas, Eduardo Pérez Evaluation Of The Phase Composition Of (NH4)2SO4 + (NH4)H2PO4 Mixtures By X-Ray Diffractometry Journal Of Alloys And Compounds, 2009, 475, 686-692.
AÑO 2008
J. Perez, A. Espinosa, J. M. Galiana, E. Perez, J. L. Serrano, A. Cabeza, M. A. G. Aranda, Crystal packing in Di-(m-OH)-ortho-palladated complexes - A DFT insight into the molecular structure and solid-state interactions. European Journal of Inorganic Chemistry 2008, 3687-3697.
J. Perez, L. Garcia, R. Carrascosa, E. Perez, J. L. Serrano, Solid state conformational preferences in transition metal complexes double bridged by phosphate and related ligands. Polyhedron 2008, 27 2487-2493.
J. L. Serrano, L. Garcia, J. Perez, E. Perez, J. Garcia, G. Sanchez, G. Lopez, M. Liu, Reactivity Towards Acidic Protic Ligands of Cyclopalladated Di-m-hydroxo Complexes. European Journal of Inorganic Chemistry 2008, 4797-4806.
J. L. Serrano, L. Garcia, J. Perez, E. Perez, J. Garcia, G. Sanchez, G. Lopez, I. J. S. Fairlamb, M. Liu, Synthesis and characterization of new oxazoline-based palladacycles with bridging or terminal imidate ligands. Crystal structures of [Pd(dibromomaleimidate)(Phox)(PPh3)] and [Pd(glutarimidate)(Phox)(PPh3)] (Phox=2-(2-oxazolinyl)phenyl)). Polyhedron 2008, 27 1699-1706.
M Dolores Santana, Gabriel García, Consuelo Vicente-Hernández, Luis García ,José Pérez, Teófilo Rojo And Luis Lezama, N,N’-Bis(Substituted-Phenyl)Oxamides And Their Dinuclear Pentacoordinate Nickel(II) Complexes, Journal Of Organometallic Chemistry. 2008, 693, 2009-2016.
M.D. Santana, L. López-Bonet, G. García, L. García, J. Pérez, M. Liu, Hydrogen Bonding And Anion Binding In Structures Of Tris(Pyrazolyl)Boratenickel(II) And Phosphate Esters. Eur. J. Inorg. Chem. 2008, 4012-4018.
AÑO 2007
M. Kessler, J. Perez, M. C. Bueso, L. Garcia, E. Perez, J. L. Serrano, R. Carrascosa, Probabilistic model-based methodology for the conformational study of cyclic systems: application to copper complexes double-bridged by phosphate and related ligands. Acta Crystallographica Section B-Structural Science 2007, 63 869-878.
J. Perez, J. L. Serrano, J. M. Galiana, F. L. Cumbrera, A. L. Ortiz, G. Sanchez, J. Garcia,Structure determination of di-mu-hydroxo-bis[(2-(2-pyridyl)phenyl-kappa N-2,C-1)palladium(II)] by X-ray powder diffractometry. Acta Crystallographica Section B-Structural Science 2007, 63 75-80.
M. Dolores Santana, Gabriel García, Gregorio López, Abel Lozano, Consuelo Vicente, Luis García And José Pérez. Preparation, Crystal Structure And Nmr Characterization Of Substituted-Benzoate Complexes Nickel(Ii)-N3-Macrocycles Polyhedron. 2007, 26 1029-1036.
M. Dolores Santana, Magalí Sáez-Ayala, Luis García, José Pérez And Gabriel García. Preparation Of Thiocarboxylate, Thiocarbamate And Xanthate Complexes Of Pentacoordinate Nickel(II): Insertion Of Heterocumulenes Into Nickel(II) Hydroxido Complexes, Eur. J. Inorg. Chem. 2007, 4628-4636.
J. Perez, L. Garcia, R. Carrascosa, E. Perez, J. L. Serrano, G. Sanchez, G. Garcia, M. D. Santana, L. Lopez, J. Garcia, Solid state conformational features of homodinuclear nickel complexes double bridged by phosphate esters and related ligands. Zeitschrift fur Anorganische und Allgemeine Chemie 2007, 633 1869-1874.
AÑO 2006
A. Abel Lozano, Magalí Sáez, José Pérez, Luis García, Luis Lezama, Teófilo Rojo, Gregorio López, Gabriel García And Mª Dolores Santana. Structure And Magnetic Properties Of Carbonate-Bridged Five-Coordinate Nickel(II) Complexes Controlled By Solvent Effect. Dalton Transactions. 2006, 3906-3911.
C. M. Crawforth, I. J. S. Fairlamb, A. R. Kapdi, J. L. Serrano, R. J. K. Taylor, G. Sanchez, Air-stable, phosphine-free anionic palladacyclopentadienyl catalysts: Remarkable halide and pseudohalide effects in Stille coupling. Advanced Synthesis & Catalysis 2006, 348 405-412.
I. J. S. Fairlamb, R. J. K. Taylor, J. L. Serrano, G. Sanchez, Halide and pseudohalide effects in Pd-catalysed cross-coupling reactions. New Journal of Chemistry 2006, 30 1695-1704.
G. Sanchez, J. Garcia, D. Meseguer, J. L. Serrano, L. Garcia, J. Perez, G. Lopez, New pentafluorophenyl complexes with phosphine-amide ligands. Inorganica Chimica Acta 2006, 359 1650-1658.
AÑO 2005
J. Perez, K. Nolsoe, M. Kessler, L. Garcia, E. Perez, J. L. Serrano, Bayesian methods for the conformational classification of eight-membered rings. Acta Crystallographica Section B-Structural Science 2005, 61 585-594.
J. Perez, L. Garcia, M. Kessler, K. Nolsoe, E. Perez, J. L. Serrano, J. F. Martinez, R. Carrascosa, Solid state conformational classification of eight-membered rings in copper complexes double bridged by phosphate, phosphonate or phosphinate ligands. Inorganica Chimica Acta 2005, 358 2432-2436.
José Ruiz, María Dolores Santana, Abel Lozano, Consuelo Vicente, Gabriel García, Gregorio López, José Pérez And Luis García. Synthesis And Characterization Of Heterotrinuclear Complexes Of Nickel And Palladium With Pyridinecarboxylate As Bridging Ligands. European Journal Of Inorganic Chemistry. 2005, 3049-3056.
G. Sanchez, J. Vives, G. Lopez, J. L. Serrano, L. Garcia, J. Perez, Exploring the reactivity towards acidic protic ligands of the di-mu-hydroxo complex [NBu4]2[Pd2{C4(COOMe)4}2(m-OH)2]: A convenient precursor in the preparation of new palladacyclopentadiene complexes. European Journal of Inorganic Chemistry 2005, 2360-2367.
AÑO 2004
J. Perez, J. F. Martinez, L. Garcia, E. Perez, J. L. Serrano, G. Sanchez, Solid state conformational study of complexes containing the (o-P-C6H4-C=N-kappa N-2,P) palladium six-membered chelated ring. Inorganica Chimica Acta 2004, 357 3588-3594.
J. L. Serrano, I. J. S. Fairlamb, G. Sanchez, L. Garcia, J. Perez, J. Vives, G. Lopez, C. M. Crawforth, R. J. K. Taylor, Palladacyclopentadiene complexes with mono- and didentate imidato ligands: Synthesis, hemilabile behaviour and catalytic application in the Stille reaction. European Journal of Inorganic Chemistry 2004, 2706-2715
I. J. S. Fairlamb, A. R. Kapdi, A. F. Lee, G. Sanchez, G. Lopez, J. L. Serrano, L. Garcia, J. Perez, E. Perez, Mono- and binuclear cyclometallated palladium(II) complexes containing bridging (N,O-) and terminal (N-) imidate ligands: Air stable, thermally robust and recyclable catalysts for cross-coupling processes. Dalton Transactions 2004, 3970-3981
M. Dolores Santana, Gabriel García, A. Abel Lozano, Gregorio López, José Tudela, José Pérez, Luis García, Luis Lezama and Teófilo Rojo. Pentacoordinate Nickel(II) Complexes Double Bridged By Phosphate Ester Or Phosphinate Ligands: Spectroscopic, Structural, Kinetic And Magnetic Studies. 2004, Chem. Eur. J., 10 1738-1746
G. Sanchez, J. Garcia, D. Meseguer, J. L. Serrano, L. Garcia, J. Perez, G. Lopez, New palladacyclic complexes with pyridylphosphine ligands: crystal structures of [Pd(Azb)(Ph2POCH2Py-P,N)][PF6] and [Pd(Phpy)(Ph2PNHPy-P,N)][PF6]. Inorganica Chimica Acta 2004, 357 4568-4576.
G. Sanchez, J. Garcia, D. J. Meseguer, J. L. Serrano, J. Perez, E. Molins, G. Lopez, Organometallic nickel(II) complexes with dithiophosphate, dithiophosphonate and monothiophosphonate ligands. Inorganica Chimica Acta 2004, 357 677-683